The author has drawn on his own research and the current literature to ensure that appropriate attention is given to topics across the range of modern organic chemistry. The text is unique in its inclusion of a chapter on reactions mediated or catalyzed by transition metals, an area in which mechanistic understanding is now essential. Relatively new topics such as olefin metathesis and cycloaromatization are covered without giving short shrift to more traditional areas such as carbonyl chemistry. The text assumes a basic knowledge of organic chemistry. It can be used either in a formal course or by students working on their own, and will be particularly useful for graduate students studying for qualifying examinations. It will also be useful to students and researchers in biochemistry, pharmacology, and inorganic chemistry.
"This is an excellent and well-presented work.... The author ... has succeeded well in treating the central ideas of reactivity and selectivity in an integrated whole. The clear style of writing, the well chosen examples, and the ... concise summaries of the main points provided at the end of each chapter should enable the reader to easily consolidate what has been learned.... The book is indeed a little work of art."
-- Jens Hartung, Angewandte Chemie International Edition
"I have taught a one-credit course with this book for three years, and, uniformly, the students have rated this book highly for its clarity and for the scope of the problems. ... This book does an excellent job at its stated goal: 'to teach students to come up with reasonable mechanisms for reactions they have never seen before.'"
-- Amy Howell, Synthesis
"I have just finished my first year of graduate studies in organic chemistry at Duke University. I just wanted to let you know how much your book got me through the past year of course work.... When it came to mechanisms, I found the clarity and thoroughness I needed only in your book. It was impressive how you were able to present so much information in a clear and comprehensive manner yet keep the book so manageable in size. In addition to the text, I also was able to benefit from the problems.... Great practice!! The on-line answers are much better than looking up answers by reference.... I am reading it again this summer in preparation for my preliminary exam next spring."
-- David Gooden
Assuming a basic knowledge about quantum mechanics, the authors link their explanations to recent experimental investigations where Molecular Quantum Dynamics proved successful and necessary for the understanding of the experimental results. Examples including reactive scattering, photochemistry, tunneling, femto- and attosecond chemistry and spectroscopy, cold chemistry or crossed-beam experiments illustrate the power of the method. The book restricts complicated formalism to the necessary and in a self-contained and clearly explained way, offering the reader an introduction to, and instructions for, practical exercises. Continuative explanation and math are optionally supplemented for the interested reader.
The reader learns how to apply example simulations with the MCTDH program package (Multi Configuration Time Dependent Hartree calculations). Readers can thus obtain the tools to run their own simulations and apply them to their problems. Selected scripts and program code from the examples are made available as supplementary material.
This book bridges the gap between the existing textbooks on fundamental theoretical chemistry and research monographs focusing on sophisticated applications. It is a must-read for everyone who wants to gain a sound understanding of Molecular Quantum Dynamics simulations and to obtain basic experience in running their own simulations.
Detailed descriptions and analysis of the key properties of packaging films are provided from both an engineering and scientific perspective. End-use effects are also covered in detail, providing key insights into the way the products being packaged influence film properties and design.
The book bridges the gap between key scientific literature and the practical challenges faced by the flexible packaging industry, providing essential scientific insights, best practice techniques, environmental sustainability information, and key principles of structure design to enable engineers and scientists to deliver superior products with reduced development time and cost.Provides essential information on all aspects of multilayer films in flexible packagingAids in material selection and processing, shortening development times and delivering stronger productsBridges the gap between scientific principles and key challenges in the packaging industry, with practical explanations to assist practitioners in overcoming those challenges
Now fully revised, Polymer Science and Technology, Third Edition, systematically reviews the field’s current state and emerging advances. Leading polymer specialist Joel R. Fried offers modern coverage of both processing principles and applications in multiple industries, including medicine, biotechnology, chemicals, and electronics.
This edition’s new and expanded coverage ranges from advanced synthesis to the latest drug delivery applications. New topics include controlled radical polymerization, click chemistry, green chemistry, block copolymers, nanofillers, electrospinning, and more.
A brand-new chapter offers extensive guidance for predicting polymer properties, including additional coverage of group correlations, and new discussions of the use of topological indices and neural networks. This is also the first introductory polymer text to fully explain computational polymer science, including molecular dynamics and Monte Carlo methods. Simulation concepts are supported with many application examples, ranging from prediction of PVT values to permeability and free volume.
Fried thoroughly covers synthetic polymer chemistry; polymer properties in solution and in melt, rubber, and solid states; and all important categories of plastics. This revised edition also adds many new calculations, end-of-chapter problems, and references.
In-depth coverage includesPolymer synthesis: step- and chain-growth; bulk, solution, suspension, emulsion, solid-state, and plasma; ionic liquids, and macromers; and genetic engineering Amorphous and crystalline states, transitions, mechanical properties, and solid-state characterization Polymers and the environment: degradation, stability, and more Additives, blends, block copolymers, and composites–including interpenetrating networks, nanocomposites, buckyballs, carbon nanotubes, graphene, and POSS Biopolymers, natural polymers, fibers, thermoplastics, elastomers, and thermosets Engineering and specialty polymers, from polycarbonates to ionic polymers and high-performance fibers Polymer rheology, processing, and modeling Correlations and simulations: group contribution, topological indices, artificial neural networks, molecular dynamics, and Monte Carlo simulations
Odor can play a significant role in the success of a product; it can decide whether a customer purchases the product in the first place, or can be the cause of complaints or returns. Similarly, in scented products, the retention of volatile components is a particular challenge and opportunity. There are several factors which have an impact on the formation of odors in plastic materials, including the properties of the polymer, use of additives in processing, exposure to radiation and oxygen, storage, and recycling.
Thirty-seven polymers and forty-one critical product groups are analyzed based on the latest research publications and patents. The book also discusses regulations related to odor in products, effects of odor on health and safety, and the effect of odors from plastic materials on indoor air quality.Analyzes the reasons behind odor formationProvides the best methods to prevent odors in various materialsContains information on testing odor changes and the relationship between odor and toxicityIncludes a comprehensive list of methods for removal of unwanted odors from plastic materials
Early chapters describe the history and nature of plastics and explain the relationship of chemical structure and properties. Preparation, structure, properties processing and applications of each class of plastics materials are then considered separately. New chapters have been added on materials selection and special polymers, including biodegradable and electroconductive polymers and thermoplastic elastomers. In addition many new plastics materials have been added throughout the text and more information has been included on testing methods and data. The sections on production/consumption statistics has also been completely updated.
Reviews of previous editions:
It's a genuine milestone in reference works...and the book is a 'must' for anyone concerned with the selection, preparation, compounding or processing of these materials' - British Plastic and Rubber
'This latest edition maintains the high standard set previously... The book s a 'must' for both student and practising technologists' - Plastics Materials
'The fourth edition of John Brydson's book carries on the splendid traditions of the previous three. As a reference book for a laboratory, sales office or student's bedroom, it is unrivalled in its comprehensive of the history, chemistry and technology of plastics'. - Reinforced Plastics
'As a reference book on the subject it is unique for its depth in such a compact form, yet allied to that it is so eminently readable. It is a working chemist's book for a working chemist.' - Journal of the Oil and Colour Chemists Association
'This is one of the most comprehensive reference books in its class.' - Polymer News, March 1996
It covers the mechanical properties of foams and foam microstructure, processing of foams, mechanical testing and analysis (using Finite element analysis). In addition, it uniquely offers a broader perspective on the actual engineering of foams and foam based (or foam including) products by including nine detailed case studies which firmly plant the theory of the book in a real world context, making it ideal for both polymer engineers and chemists and mechanical engineers and product designers.
* Complete coverage of the mechanical and design aspects of polymer foams from an acknowledged international expert: no other book is available with this breadth making this a plastics engineer's first choice for a single volume Handbook
* Polymer foams are ubiquitous in modern life, used everywhere from running shoes to furniture, and this book includes nine extensive case studies covering each key class of application, including biomechanics
* Offers a rigorous mechanical and microstructure perspective, plus a computer based chapter: Essential for engineers and designers alike.
This third edition presents thorough coverage of newly developed materials including nanocomposites. It also adds more emphasis on underlying theories, practical methods, and problem-solving skills employed in real-world applications of composite materials. Each chapter contains new examples drawn from diverse applications and additional problems to reinforce the practical relevance of key concepts.
New in The Third Edition: Contains new sections on material substitution, cost analysis, nano- and natural fibers, fiber architecture, and carbon-carbon composites Provides a new chapter on polymer-based nanocomposites Adds new sections on test methods such as fiber bundle tests and interlaminar fracture measurements Expands sections on manufacturing fundamentals, thermoplastics matrix composites, and resin transfer molding
Maintaining the trademark quality of its well-respected and authoritative predecessors, Fiber-Reinforced Composites: Materials, Manufacturing, and Design, Third Edition continues to provide a unique interdisciplinary perspective and a logical approach to understanding the latest developments in the field.
This practical guide to extrusion brings together both equipment and materials processing aspects. It covers basic and advanced topics, for reference and training, in thermoplastics processing in the extruder. Detailed reference data are provided on such important operating conditions as temperatures, start-up procedures, shear rates, pressure drops, and safety.A practical guide to the selection, design and optimization of extrusion processes and equipmentDesigned to improve production efficiency and product qualityFocuses on practical fault analysis and troubleshooting techniques
This book is divided into two parts. The chapters in Part One explore the manufacture, mechanical behavior and structural performance of marine composites, and also look at the testing of these composites and end of life environmental considerations. The chapters in Part Two then investigate the applications of marine composites, specifically for renewable energy devices, offshore oil and gas applications, rigging and sails. Underwater repair of marine composites is also reviewed.Comprehensively examines all aspects of fibre-reinforced marine composites, including the latest advances in design, manufacturing methods and performanceAssesses the environmental impacts of using fibre-reinforced composites in marine environments, including end of life considerationsReviews advanced fibre-reinforced composites for renewable energy devices, rigging, sail textiles, sail shape optimisation and offshore oil and gas applications
The book is an essential handbook for scientists and engineers working in PTFE processing industries, and for manufacturers working with fluoropolymers. It is also of use to purchasing managers and academics.Presents every aspect of the manufacturing technologies and properties of ePFTEProvides detailed coverage of ePTFE applications in apparel, medical, and surgical devices, filtration, vents, and industrial usesFollows ePFTE from its original discovery to the latest developments
The final part of the book consists of a series of appendices which provide in-depth analysis of key topics with detailed technical data and worked examples which is an invaluable reference in itself for anyone concerned with the behaviour, performance and economics of a textile mill.
Handbook of yarn production: technology, science and economics is a standard work for both yarn manufacturers and those researching and studying in this important area of the textile industry.A practical and authoritative new handbook for yarn manufacturingShows how problems can arise and how to deal with themIncludes invaluable technical data, calculations, worked examples and case studies
This book is particularly designed for scientists and engineers working in various industries, including food, consumer products, pharmaceuticals, medicine, agriculture, nutraceuticals, dietary supplements, cosmetics, flavors, and fragrances. It offers a broad perspective on a variety of applications and processes, providing research information, figures, tables, illustrations, and references.
The book also lays the groundwork for further advancements in encapsulation technology and controlled release applications. Catering to professionals, researchers, students, and general readers in academia, industry, and research institutions, the Handbook of Encapsulation and Controlled Release is a much-needed reference on the state of the field and an authoritative resource for continued research and development in encapsulation and controlled release technologies.
Castable Polyurethane Elastomers explains the production process of polyurethane components from both the theoretical and practical point of view. It describes the underlying concepts for the raw material supplier recommendations and explains how to achieve application-specific properties in polyurethane. The book explains the production of prepolymers with special focus on health and safety issues. It presents the different types of methods available on both the micro and macro levels and explains the rationale behind choosing the system needed to create a cost-effective, application-specific product.
Offering an inside look at the logic behind the formation of polyurethane components, Castable Polyurethane Elastomers enables materials scientists, engineers, and chemists to understand the total production process and reproduce the procedures to achieve desired results.
Examining polymers at the molecular level, the book first discusses their inherent properties and how their end-use properties can be influenced through changes in the molecular architecture or incorporation of various fillers and additives. The authors coherently present a wide spectrum of topics by sequentially introducing structural aspects, properties, and applications. They then proceed to explore the mechanical, electrical, optical, and thermal properties of polymers, providing theoretical derivations where necessary as well as explanations on molecular and structural features. To identify the principles involved, the book also furnishes the bases of many standard test methods according to ASTM and BS 2782 specifications.
New Edition Offers Improved Framework for Understanding Polymers
Written by well-established professors in the field, Polymer Chemistry, Second Edition provides a well-rounded and articulate examination of polymer properties at the molecular level. It focuses on fundamental principles based on underlying chemical structures, polymer synthesis, characterization, and properties.
Consistent with the previous edition, the authors emphasize the logical progression of concepts, rather than presenting just a catalog of facts. The book covers topics that appear prominently in current polymer science journals. It also provides mathematical tools as needed, and fully derived problems for advanced calculations. This new edition integrates new theories and experiments made possible by advances in instrumentation. It adds new chapters on controlled polymerization and chain conformations while expanding and updating material on topics such as catalysis and synthesis, viscoelasticity, rubber elasticity, glass transition, crystallization, solution properties, thermodynamics, and light scattering.
Polymer Chemistry, Second Edition offers a logical presentation of topics that can be scaled to meet the needs of introductory as well as more advanced courses in chemistry, materials science, and chemical engineering.
The authors present key research outcomes on the design and development of functional apparel designed for high-performance sportswear that explore smart materials, impact-resistant fabrics and pressure sensing. They consider the use of 3-D body scanning and its influence on pattern engineering for apparel product development; highlight the widely used fiber types for sportswear and the importance of fiber blends and their performance, and discuss the relevance of fabric structure and its interaction with the human body. The book also presents research on moisture management and temperature regulation and analyzes the performance and development of smart sportswear intended for monitoring health and performance for a range of end uses.
A definitive guide detailing the future of functional clothing and sportswear, this book:
Describes how to design and develop functional clothing for sportswear Reflects current research outcomes and industry requirements Clarifies with visual illustration, practical examples, and case studies an understanding of techniques and concepts Explores specifics of garment design such as fit, shape, function, fashion and design Focuses on a commitment to designing ethical and sustainable products