The Bases of Chemical Thermodynamics: Volume 2

Michael Grätzel · Pierre Infelta

jan. 2000 · The Bases of Chemical Thermodynamics Bog 2 · Universal-Publishers

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Volume 2: In this volume, the tools necessary to study and understand systems in which chemical reactions can take place are developed. The variables of reaction are the keys to this understanding. Criteria for chemical equilibrium are established. It is shown how chemical reactions can provide work as, for example, in batteries. For complex systems, the number of independent reactions and their nature have to be determined systematically. The effect of external factors on chemical equilibria is analyzed and illustrated. The formalism necessary to study ideal and real solutions is provided. The various standard states in use and the corresponding activity coefficients are clearly defined. The statistical aspect of thermodynamics is best understood once students are familiar with the rest of the book and, for this reason, is treated in the last chapter.